Electrochemical Deposition of Multicomponent Mixed Metal Oxides on rGO/Ni Foam for All-Solid-State Asymmetric Supercapacitor Device: Mn, Co, and Ni Oxides with Ag Doping

نویسندگان

چکیده

In this study, an asymmetric supercapacitor (ASSC) device is assembled by the deposition and annealing of silver-doped mixed metal oxides on reduced graphene oxide (rGO)/Ni foam activated carbon (AC) Ni as positive negative electrodes, respectively. The best performing Ag:MnCoNiO active material synthesized rGO/Ni using chronopotentiometry combined with heat treatment. XRD study clearly confirms crystalline nature electrode MnCo2O4 MnNi2O4 phases. FT-IR XPS studies revealed formation Ag:MnCoNiO/rGO foam. SEM images show a thin-film layer fabricated surface properties were tested in two- three-electrode configurations, cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), electrochemical impedance spectroscopy (EIS) experiments 6 M KOH aqueous electrolyte. configuration, reversible faradic reactions can be observed potential range 0.0 +0.6 V vs. Hg/HgSO4. two-electrode system exhibits maximum energy density 45.5 Wh kg−1 provides power 4.5 kW kg−1. results showed that doping Ag MnCoNiO shows promising properties, achieved very simple fabrication process. showcase synergistic effects multiple-component oxides, leading to improved supercapacitive properties.

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ژورنال

عنوان ژورنال: Energies

سال: 2022

ISSN: ['1996-1073']

DOI: https://doi.org/10.3390/en15228559